SPRAYON PRODUCTS -- UPSIDE DOWN MARKING PAINTS 03620 CAUTION BLUE -- -
===================== Product Identification ===================== Product ID:UPSIDE DOWN MARKING PAINTS 03620 CAUTION BLUE MSDS Date:07/01/1994 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:SPRAYON PRODUCTS Address:31500 SOLON ROAD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-777-2966 Emergency Phone Num:216-292-7400 Resp. Party Other MSDS Num.:94B CAGE:09800 === Contractor Identification === Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC. Address:26300 FARGO AVENUE Box:City:BEDFORD HEIGHTS State:OH ZIP:44146 Country:US Phone:216-292-7400 OR 216-595-8634 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE VP: 760 MM HG CAS:74-98-6 RTECS #:TX2275000 = Wt:8. OSHA PEL:1800 MG/M3;1000 PPM Ingred Name:2-METHYLPROPANE (MFR'S CAS #75-29-5) VP: 760 MM HG CAS:75-28-5 RTECS #:TI4300000 = Wt:8. Ingred Name:NAPHTHA (PETROLEUM), HYDROTREATED HEAVY; (V.M.&P. NAPHTHA) VP: 12 MM HG CAS:64742-48-9 = Wt:16. Ingred Name:DISTILLATES (PETROLEUM), HYDROTREATED LIGHT; (MINERAL SPIRITS) CAS:64742-47-8 RTECS #:OA5504000 = Wt:6. Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:11. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CNTCT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS, FOLLOW RECOMS FOR PROPER USE, VENT & PPE. ACUTE: IRRIT OF EYES, SKIN & RESP SYSTEM. MAY CAUSE NERVOUS SYSTEM D EPRESS. EXTREME OVEREXP MAY RESULT IN UNCON & POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPS/SPRAY MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY IND ICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC: PRLNGD & RPTD EXPOSURE TO HEXANE MAY CAUSE DAMAGE TO NERVE TISSUE OF THE ARMS & LEGS (PERIPHERAL NEUROPATHY), RESULTING IN MUSCULAR WEAK & LOSS OF SENSAT ION. THIS EFFECT (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZS: MAY BE INCREASED BY THE PRESENCE OF METHYL ETHYL KETONE. PRLNGD OVEREXP TO SOLVENT INGREDS LISTED MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRODUCTI VE SYSTEMS. REPORTS HAVE ASSOC RPTD & PRLNGD OVEREXP TO SOLVENTS W/PERM BRAIN & NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WA TER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<-17.8C, 0.F Lower Limits:0.7% Upper Limits:12.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSUR E BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. RED LABEL - EXTREMELY FLAMABLE, FLASH BELOW 21F. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:NFPA CODE 30B - LEVEL 2 AEROSOLS. CONTENTS ARE EXTREMELY FLAMABLE. KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE: KEE P AREA VENTD - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF (SUPDAT) Other Precautions:INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN INGRED SECTION) WHICH MAY (O THER INFO) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINS MATLS LISTED IN INGRED SECTION. WHEN SANDIN G OR ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM THIS PROD, UNDERLYING PAINT OR ABRASIVE. Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS LISTED IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94, 1910.107, 1910.108. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Supplemental Safety and Health HNDLG/STOR PRECS: STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMP ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:<-17.8C, 0.F B.P. Text:<0-395F Vapor Pres:SEE INGREDS Vapor Density:HVR/AIR Volatile Org Content %:49 Evaporation Rate & Reference:FASTER THAN ETHER Percent Volatiles by Volume:>75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METAL LISTED IN INGREDIENT SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBER. DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STAT E AND LOCAL REGULATIONS REGARDING POLLUTION. =================== MSDS Transport Information =================== Transport Information:DOMESTIC OTHER THAN AIR (DOT): SHIPPING NAME: INITIATING EXPLOSIVE; HAZARD CLASS: CLASS A EXPLOSIVE; UN/NA NUMBER: UN0129; DOT LABEL(S): EXPLOSIVE A; SPECIAL INFORMATION: COLLOIDAL LEAD AZIDE - DOT-E 2462; DOT PLACARD: EXPLOSIVES A. INTERNATIONAL WATER OR AIR (IMO/ICAO): SHIPPING NAME: IMO: LEAD AZIDE; HAZARD CLASS: 1.1A; UN NUMBER: 0129; IMO/CIAO LABEL: EXPLOSIVE; SPECIAL INFORMATION: IATA/ICAO; LEAD AZIDE, WETTED, FORBIDDEN. ===================== Regulatory Information ===================== SARA Title III Information:INGREDIENTS SUBJECT TO THE REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 313, 40 CFR 372.65 C: XYLENE, ACETONE, BARIUM SULFATE. Federal Regulatory Information:THIS MSDS CONFORMS TO THE HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200(G)(4), FOR SIILAR COMPLEX MIXTURES. HMIS RATINGS (HEATLH-2; FLAMABILITY-4; REACTIVITY-0). State Regulatory Information:SEVERAL OF THESE PRODUCTS CONTAIN A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.